← Separation Techniques

Revision

The whole chapter on one page

Use it the night before, not instead of the lessons.

The decision table — learn this first

What differs between the constituents? Technique
One is magnetic, the other is notmagnetic attraction
Different particle sizes — an insoluble solid in a liquidfiltration
A dissolved solid, and you want the solidevaporation
Different boiling points, and you want the liquiddistillation
They dissolve to different extents in a solventchromatography

The principle behind it: the constituents of a mixture retain their physical properties, and the differences between those properties are what let us separate them. Other factors in the choice: cost · reliability · environmental impact.

The five definitions

Magnetic attractionSeparates magnetic from non-magnetic substances. Iron and steel are magnetic; aluminium, copper, plastic, glass and rubber are not.
FiltrationSeparates substances of different particle sizes using a sieve. Particles smaller than the pores pass through; bigger ones are retained. Solid on the paper = residue. Liquid through = filtrate.
EvaporationObtains a dissolved solid (solute) from a liquid (solvent). Works because the solvent changes state at a much lower temperature than the solute. The liquid is lost.
DistillationSeparates substances with different boiling points by boiling and condensation. The substance with the lowest boiling point vaporises first. Collected liquid = distillate.
ChromatographySeparates substances that dissolve to different extents in a solvent. More soluble → travels further. Insoluble → stays on the start line. The finished paper = chromatogram.

Evaporation vs distillation — the pair that gets confused

EvaporationDistillation
You collect the solidYou collect the liquid
Liquid escapes as vapour and is lostVapour is condensed and collected
Dish, gauze, flameFlask, thermometer, condenser with cold water running through, beaker
Salt from seawaterPure water from seawater

The deciding question is never "what is in the mixture?" but "what do I want to collect?"

Applications to have ready

TechniqueApplications
Magnetic attractionRemoving iron from scrap metal in a scrapyard so it can be reused or recycled. Left behind: glass mirrors, rubber tyres, plastic bumpers.
FiltrationTea strainer (retains tea leaves) · siltation pond (sand and rocks of different sizes filter groundwater) · your nose (nostril hairs and mucus trap large particles) · waterworks · Gardens by the Bay (aquatic plants filter rainwater).
EvaporationSalt production in salt pans under the sun · preserving food — herbs, spices, dried shrimp, ikan bilis · vacuum drying (air removed so water evaporates faster; preferred because normal drying spoils flavour).
DistillationPerfumes · distilled water · food flavourings (citrus oil, herb and spice extracts) · drinking water from seawater · oil refineries on Pulau Bukom and Jurong Island making fuels from crude oil.
ChromatographyIdentifying colours in dyes · identifying coloured substances in food · detecting water pollutants · SFA food testing by gas chromatography (a gas as the solvent).

The distillation apparatus, in order

1. Salt solution in the distillation flask is heated until it boils. Boiling chips smoothen the boiling.
2. Water changes into steam, which passes through the condenser. The condenser has cold water running through it continuously.
3. The steam cools and condenses into pure water — the distillate. The salt remains in the flask.

The thermometer at the neck reads the boiling point of whatever is vaporising — 100 °C while water comes across.

Distillation in nature: the water cycle (evaporation then condensation). A solar still uses the same processes to collect water where supply is irregular.

Water in Singapore

The Four National Taps: water from local catchment · imported water · NEWater · desalinated water.

Reverse osmosis: pre-treated seawater is pumped through partially permeable membranes at high pressure. Very small pores let water particles through but not salt particles, microorganisms or chemical contaminants.

Water stress: in 2015 the WRI ranked Singapore among the most water-stressed countries, and one of eight most likely to face supply disruptions by 2040.

Conserving water — reduce wastage and reuse water. Also protect resources by not throwing litter or releasing animals into waterways and reservoirs.