← Chemical Changes

Lesson 7 of 8 · Textbook 11.3 · Guide 11.6–11.7

Electrolysis and photosynthesis

Two chemical changes driven by something other than heat — one by electricity, one by light.

Electrolysis

Electrolysis is the breaking down of substances using electrical energy. It is one of the "breaking down" chemical changes, but the trigger is an electric current rather than heat.

Splitting water

When electricity is passed through water containing some dissolved salt or acid, using platinum electrodes, the water is decomposed into its elements:

water  --electricity-->  hydrogen + oxygen

Two volumes of hydrogen are produced for every one volume of oxygen. The hydrogen forms at the negative electrode and the oxygen at the positive electrode.

Testing the products The oxygen can be identified with a glowing splint — it rekindles into a flame. The hydrogen gives a squeaky "pop" with a burning splint.

Run the cell yourself

Pick what to put in the cell, then switch the current on. Watch the rate of bubbling at each electrode.

Electrolysis cell

+ negative electrode positive electrode

At negative electrode
At positive electrode

Splitting molten sodium chloride

Sodium chloride can also be decomposed into its elements by the electrolysis of molten sodium chloride, with graphite rods as the electrodes:

sodium chloride  --electricity-->  sodium + chlorine

Sodium metal forms at the negative electrode and chlorine gas at the positive one. In industry, an iron screen keeps the two apart so they cannot meet and react back together.

Electroplating

Electroplating uses electrolysis to coat an object with a thin layer of metal — to protect it, to make it look better, or to improve its electrical conductivity.

The rule to remember: the object being plated is always the negative electrode, and the metal used for coating is the positive electrode. Positively charged metal particles move through the solution and build up on the object layer by layer.

A catch worth knowing If the object does not conduct electricity — a plastic spoon, or an orchid — it must first be coated with a layer of an electrical conductor such as graphite or copper before it can be electroplated at all.

Electrolysis as a redox reaction Extension

Electrolysis involves both oxidation and reduction happening at the same time. Oxidation occurs at the positive electrode (the anode) while reduction occurs at the negative electrode (the cathode).

At the anode (+) At the cathode (−)
WaterOH⁻ lose electrons → O₂ and H₂OH⁺ gain electrons → H₂
Molten NaClCl⁻ lose electrons → Cl₂Na⁺ gain electrons → Na

Photosynthesis

Photosynthesis is the process by which plants manufacture food, using carbon dioxide, water and light energy from the Sun. Chlorophyll in the leaves absorbs the light energy needed to drive the reaction.

carbon dioxide + water  --light-->  sugar (glucose) + oxygen

It is vital for the survival of all living beings, including humans and animals — and plants themselves — because oxygen is created as a by-product.

Photosynthesis is respiration in reverse Compare the two word equations:

photosynthesis: carbon dioxide + water → sugar + oxygen

respiration: sugar + oxygen → carbon dioxide + water

They are exact opposites. Respiration, decomposition by bacteria, and the combustion of fossil fuels all release carbon dioxide; photosynthesis absorbs it. That balance is why planting trees is encouraged to help slow climate change — Singapore has its own annual tree-planting day.

Check yourself